Pharma and Fine Chemical Reagents
Trialkylphosphines are widely used as processing aides for a
variety of common reactions employed by the pharmaceutical and
fine chemical industries. These reactions include the
Staudinger, Mitsunobu and Wittig reactions used for amine,
ester and olefin synthesis. In addition, tertiary
alkylphosphines are powerful reducing agents for disulfide
reduction. Tertiary alkylphosphines are also used at a
catalytic level in transformations such as the Baylis-Hillman
and Rauhut-Currier reactions. As opposed to triphenylphosphine,
the alkyl derivatives generally provide faster kinetics,
improved selectivity and ease of work-up. Trialkylphosphines
are marketed under the Cytec CYTOP® organophosphine trade name
such as CYTOP 320 (triethylphosphine), CYTOP 340 (tributryphosphine),
CYTOP 341 (triisobutylphosphine), CYTOP 380 (trioctylphosphine)
and CYTOP 208 (tris(3-hydroxypropyl)phosphine).
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|
Trade Name |
C.A.S. Number |
Chemical Name |
Product
Datasheets |
|
CYTOP 141 |
[4023-52-3] |
mono isobutylphosphine |
|
|
CYTOP 142 |
[2501-94-2] |
mono tert-butylphosphine |
|
|
CYTOP 155 |
[15573-36-1] |
mono cy-pentylphosphine |
|
|
CYTOP 166 |
[822-68-4] |
mono cy-hexylphosphine |
|
|
CYTOP 183 |
[82164-75-8] |
mono (2,4,4-trimethylpentyl)phosphine |
|
|
CYTOP 241 |
[4006-38-6] |
di isobutylphosphine |
|
|
CYTOP 242 |
[819-19-2] |
di tert-butylphosphine |
|
|
CYTOP 255 |
[39864-68-1] |
di cy-pentylphosphine |
|
|
CYTOP 266 |
[829-84-5] |
di cy-hexylphosphine |
|
|
CYTOP 222 |
[148432-44-4] |
di norbornylphosphine |
|
|
CYTOP 170 |
[328952-55-8] |
2-phosphabicyclo[3.3.1]nonane, 4,8-dimethyl |
|
|
CYTOP 216 |
[26088-25-5] |
1,3,5,7-tetramethyl-2,4,8
trioxa-6-phosphaadamantane |
|
|
CYTOP 320 |
[554-70-1] |
triethylphosphine |
Download PDF |
|
CYTOP 330 |
[2234-97-1] |
tripropylphosphine |
|
|
CYTOP 340 |
[998-40-3] |
tributylphosphine |
Download PDF |
|
CYTOP 341 |
[4125-25-1] |
triisobutylphosphine |
|
|
CYTOP 355 |
[7650-88-6] |
tri cy-pentylphosphine |
Download PDF |
|
CYTOP 360 |
[4168-73-4] |
trihexylphosphine |
Download PDF |
|
CYTOP 366 |
[2622-14-2] |
tri cy-hexylphosphine |
|
|
CYTOP 380 |
[4731-53-7] |
trioctylphosphine |
|
|
CYTOP 331 |
[4023-53-4] |
tris(2-cyanoethyl)phosphine |
|
|
CYTOP 208 |
[4706-17-6] |
tris(3-hydroxypropyl)phosphine |
|
|
CYTOP 198 |
[289622-48-6] |
9-isobutyl-9-phosphabicyclo[3.3.1]nonane |
|
|
CYTOP 224 |
[106872-07-5] |
9-cycloheyyl-9-phosphabicyclo[3.3.1]nonane |
|
|
CYTOP 292 |
[97739-46-3] |
1,3,5,7-tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane |
Download PDF |
|
CYTOP 228 |
[93428-50-3] |
4-phosphorinanone-1-isobutyl-2,2,6,6-tetramethyl |
|
|
CYTOP 318 |
[146091-21-6] |
1,2-(bis-isobutylphosphino)ethane |
|
|
